Highly active and tunable catalysts for O2 evolution from water based on mononuclear ruthenium(II) monoaquo complexes.
نویسندگان
چکیده
The catalytic activity of [Ru(tpy)(bpy)OH(2)](2+) (tpy = 2,2':6',2''-terpyridine and bpy = 2,2'-bipyridine) increased by a 4'-substituted ethoxy group on the tpy ligand by more than one order of magnitude to give 1.1 × 10(-1) s(-1) of catalyst turnover frequency, which is comparable with the hitherto-reported champion data.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 15 شماره
صفحات -
تاریخ انتشار 2011